confusion regarding carboxyl group dissociation on SOM and CEC
Fragment of a discussion from Course talk:APBI200
thanks! but where does the OH- in the first equation come from?
Katrine
The OH- from the first equation comes from:
In soil, when compounds containing base forming cations (ie. fine minerals) meets water, they will hydrolyze:
Na2CO3 + H2O --> 2Na+ + HCO3- + OH-
The Na+ then binds to the soil cation exchange sites. OH- is what makes the soil alkaline. This OH- then reacts with the soil colloid functional group (R-COOH) to make R-COO- + H20 (first equation)