If a vector lies in the line of rotation, after multiplying the rotational matrix on the vector, the vector stays the same.
That is to say if we denote this vector by , then we have
Equivalently we are looking for eigenvector corresponding to eigenvalue 1. We need to solve characteristic equation
That is
By row reduction we have
Thus
and
, i.e.,
So the eigenvector is
which is the vector direction of axis.