For lab 11 we need a conversion factor to go from dV/dt to dCO2/dt which was supposed to be on the multi-meter box. I don't think the forest group recorded it - is there a way to obtain it?
Hello, In lab 3, what does "assay wells" in Fassay refer to? Which wells are these exactly?
Thank you Diana
Does DTPA-TEA method equally extract irons in both ferrous and ferric states? I thought it could explain the low Fe in Bf and Bhf of Podzol if DTPA-TEA method favors extracting ferrous states, assuming Fe in Podzolic B is predominantly in ferric state.
Good question. And yes, DTPA-TEA method does extract bot ferrous and ferric Fe forms, since both of them are plant-available forms.
OK. Thank you, Maja! I think I'm going to figure out something else...
But if the DTPA-TEA extracts both, low Fe in Podzol B cannot be explained like this.
I'm kind of looking at this by the opposite way. Fe in the Podzol B appears relatively low because most of other mineral soils have very high Fe. Crescent, Delta, Ladner soils are underlain by rocks containing a high concentration of sulfide minerals which most likely is composed of pyrite. The oxidation of pyrite increases Fe2+ in soil solution which is further oxidized to become Fe3+ both of which are extracted with DEPA-TEA, which can also explain why Gleysol in this area is so acidic in natural conditions.
But, also, I think Fe2+ and Fe3+ well-solubilized by DOM are lost from Podzol B by lateral seepage during the wet season. As for the Podzol Ap, I think some disturbances after the clearing of original forest increased Fe content.
It just dawned on me that Monday (November 13) is a holiday (in lieu of the Remembrance Day), so I'm happy to extend your deadline for the soil chemistry report to Nov 13 by midnight.
Also, I will not be done with marking of lab #7 assignments until Sunday morning, so that is another reason for this additional deadline extension.
Q. Is it okay to use only one pH value (eg. measured in CaCl2) and one organic matter value (eg. oven dried) for each sample in our analyses?
A. Oven-dried value for soil organic matter is the correct value to use when reporting on soil organic matter. You were give the air-dry values so that you can determine the difference between the 2 set of values which would then allow you to comment on the hygroscopic water content.
As for 2 sets of soil pH values, you can use one of them, unless you want to discuss the difference between two sets of pH values (similar to last week's assignment).
Hi Maja, What is the unit of t electrical conductivity that we got in the last week? Should we do some calculations of the data or we just put our data directly? Thanks for your reply.
In the instruction PDF for the chemistry section summary, it says "... using ALL the data ..." Does this mean we are expected to use the phosphorus, EC, and metal contents data (DTPA-TEA) too? I was wondering this since the weekly assignments did not include the interpretation of these data.
Yes, Taku you should use those data too.
The weekly assignment did not include that data to shorten that last weekly assignment and allow you more time to work on the summary chemistry report.
I was wondering if you would consider forage grass as the same land-use as potatoes/onions. Like is it still considered agriculture land? and if it is, would a forage grass site not experience as much human management compared to the onions/potatoes which may require more management?
It said we should consider 13 samples as mineral soil or organic soil. Can we group Podzol and Solonezt together as mineral soil even they are different soil types?
I was just wondering how you determined the soil order of the 13 soil samples if the tables didn't show what order they belonged too?
I look into the background information of 13 samples. Some tell me soil orders but some not. I think the features of soil which provied by background information and connect them to the features of basic 10 soil orders, then I can figure out which order the sample belongs to.
Anyone else have ideas as to why we chose loss on ignition method? I could only come up with it being potentially cheaper than dry combustion since a special induction furnace isn't used and it can be safer than wet combustion since acids are not used.
I'm thinking maybe the product of ash that can be used for elemental analysis might be a bonus but I'm not 100% sure. If any of you have any other ideas I'd love to hear them! thanks!
I just put all crucibles and Al-boats in 3 desiccators, which are now placed next to 2 balances in MCML102A lab. You can come at any time after 9 am either tomorrow (Nov 2) or Friday (Nov 3) to weight your sample.
Once you are done weighing, discard your soil samples into one of collection bins in MCML102A
When taking samples out of desiccators, pls be careful not to spill your sample over other samples
Hello, I don't understand what exactly we need to compare in question 2.b. It says "differences in pH values obtained by the two methods". Do we need to subtract pH (water) from pH (CaCl2) and compare these differences to organic matter content?
Yes, that is exactly it. And in the discussion to accompany that comparison, you should explain why certain samples have quite a large difference between pH values determined in water and in a salt (CaCl2) and others don't. Also, what does that difference tell us about soil's capability to resist pH change when we add bases (eg lime) and acids (eg N-fertilizers) to the soil.
Dear Maja, I am confused about the features of oven-dry organic matter content. Is there any relationship between the exchangeable Al charge and oven-dry organic matter content?
Not sure to what question in lab assignment #6 are you referring to?
Here are some notes re. soil organic matter, its determination, and charge formation:
Soil organic matter content is determined by drying in a muffle furnace (not oven) and that is one of the methods of determining soil organic matter. Furthermore, soil organic matter is one of the soil components that carries quite a bit of charge, but Al is not part of structure of organic compounds. Charge on organic compounds is formed on functional groups (eg carboxyl and OH groups) and type of charge (ie negative, positive or none) is driven by pH of soil solution that surrounds organic compound in question.
The difference of value between two methods and oven-dry organic matter content. I think some components of organic matter will volatilize during oven-drying. How oven-dry organic matter content relate to the difference of value between two methods? And the difference of value should be the concentration of H charges or the number of PH?
Question #1 in the lab assignment #6 is asking to "... compare the two sets of values for soil pH and explain the differences in the values obtained by the two methods." Hence, two sets of values that should be compared are soil pH determined in water and soil pH determined in a salt (ie CaCl2).
As for determining soil organic matter by loss on ignition method, the basis for that method is that ALL organic compounds are burnt off at the temperature of 600C.
Soil pH determination is done on air-dried samples (as is the typical procedure in preparing samples for soil chemical lab analyses), not on oven-dried samples.
Dear Maja In Question #2 b), it uses oven-dry organic matter content.Why use oven-dry organic matter not air-dry organic matter?
In Friday's lecture, I explained the reason why soil organic matter determined by the loss on ignition method on air-dried samples needs to be corrected. Please take a look at the lecture notes for last Friday (Oct 26) that are posted in Connect.
There are a couple of texture data that add up to be greater than 100%. I was wondering if they were typos? Or, am I missing something... Podzol, alder forest, Cg => 102% Podzol, cultivated mid slope, C => 101% Gleysol, Delta, 7.5-15cm => 110%